The mineral marcasite P1290083
Marcasite, whose name is derived from the Arabic word for pyrite, is a common and an attractive mineral. The two minerals, marcasite and pyrite, are often confused due to their similar characteristics. Marcasite is a polymorph of pyrite which means that it has the same chemistry as pyrite but a different structure and, therefore, different symmetry and crystal shapes. The marcasite/pyrite polymorh pair is probably the most famous polymorph pair next to the diamond/graphite pair. Adding to the confusion between marcasite and pyrite is the use of the word marcasite as a jewelry trade name. The term is applied to small polished and faceted stones that are inlayed in sterling silver. But even though they are called marcasite, they are actually pyrite.
Marcasite is difficult to distinguish from pyrite when a lack of distinctive crystal habits exists. In fact, many specimens have been wrongly identified as pyrite or marcasite by even experienced mineral collectors. For many years the iron sulfide "Suns" found in Illinois coal mines were called "Marcasite Suns" (also known as "Marcasite Dollars") until X-ray studies showed them to be mostly pyrite. They have a habit that looks like marcasite. The possibility that they were originally marcasite and then later transformed into pyrite is being studied. Now they are correctly called "Pyrite Suns", but the confusion still exists. Many marcasite specimens are distinctive enough to reveal their true identity and make interesting and beautiful display specimens.
The most famous habit for marcasite is its "cock's comb" twinned habit. The crystals appear like a roster's head crest, hence the name. The habit is very distinctive and can not be mistaken for any other mineral.
Marcasite has been known to pseudomorph other minerals. A pseudomorph is an atom by atom replacement of one mineral's chemistry for another. If done subtly, the replacement can leave the old mineral's shape intact. The effect is one mineral in the shape of another, hence the term pseudomorph (Latin for false shape). Marcasite has pseudomorphed pyrite, gypsum, fluorite and others. At other times marcasite is pseudomorphed itself into the iron oxide mineral goethite. Often the replacement is only peripheral and leaves a thin skin of iron oxides on the crystals. These iron oxides are seen as an iridescence sheen and can provide marcasite specimens with quite an attractive and colorful appearance. These oxides may also have a positive effect in slowing marcasite's unfortunate deterioration.
Over a period of years, marcasite will oxidize in collections, freeing sulfur which forms sulfuric acid. The acid will then attack the paper label and even the cardboard box holding the specimen. Over a period of decades, most marcasite specimens will have disintegrated into an undesirable dust along with deteriorated paper scraps. A sulfur smell released during this reaction is often the easiest characteristic distinguishing Marcasite from Pyrite. The reaction is triggered by exposure to air and is an exothermic reaction, meaning that the reaction releases heat. This does not mean that marcasite hand specimens will feel warm to the touch, but in some marcasite rich portions of certain mines the mine walls would get too hot to touch because of this reaction. Ironically, specimens with iridescent oxide coatings have shown a resistance to deterioration and seem to survive longer than "fresh" maracasites. Either way marcasite is an interesting and attractive mineral and even with the slow deterioration can be a pleasure to own for many many years.
Marcasite can be formed as both a primary or a secondary mineral. It typically forms under low-temperature highly acidic conditions. It occurs in sedimentary rocks (shales, limestones and low grade coals) as well as in low temperature hydrothermal veins. Commonly associated minerals include pyrite, pyrrhotite, galena, sphalerite, fluorite, dolomite and calcite.[1]
As a primary mineral it forms nodules, concretions and crystals in a variety of sedimentary rock, such as at Dover, Kent, England, where it forms as sharp individual crystals and crystal groups, and nodules (similar to those shown here) in chalk.
As a secondary mineral it forms by chemical alteration of a primary mineral such as pyrrhotite or chalcopyrite.
Marcasite reacts more readily than pyrite under conditions of high humidity. The product of this disintegration is iron(II) sulfate and sulfuric acid. The hydrous iron sulfate forms a white powder consisting of the mineral melanterite, FeSO4·7H2O.[5]
This disintegration of marcasite in mineral collections is known as "pyrite decay". When a specimen goes through pyrite decay, the marcasite reacts with moisture and oxygen in the air, the sulfur oxidizing and combining with water to produce sulfuric acid that attacks other sulfide minerals and mineral labels. Low humidity (less than 60%) storage conditions prevents or slows the reaction.[6]
The mineral marcasite P1290083
Marcasite, whose name is derived from the Arabic word for pyrite, is a common and an attractive mineral. The two minerals, marcasite and pyrite, are often confused due to their similar characteristics. Marcasite is a polymorph of pyrite which means that it has the same chemistry as pyrite but a different structure and, therefore, different symmetry and crystal shapes. The marcasite/pyrite polymorh pair is probably the most famous polymorph pair next to the diamond/graphite pair. Adding to the confusion between marcasite and pyrite is the use of the word marcasite as a jewelry trade name. The term is applied to small polished and faceted stones that are inlayed in sterling silver. But even though they are called marcasite, they are actually pyrite.
Marcasite is difficult to distinguish from pyrite when a lack of distinctive crystal habits exists. In fact, many specimens have been wrongly identified as pyrite or marcasite by even experienced mineral collectors. For many years the iron sulfide "Suns" found in Illinois coal mines were called "Marcasite Suns" (also known as "Marcasite Dollars") until X-ray studies showed them to be mostly pyrite. They have a habit that looks like marcasite. The possibility that they were originally marcasite and then later transformed into pyrite is being studied. Now they are correctly called "Pyrite Suns", but the confusion still exists. Many marcasite specimens are distinctive enough to reveal their true identity and make interesting and beautiful display specimens.
The most famous habit for marcasite is its "cock's comb" twinned habit. The crystals appear like a roster's head crest, hence the name. The habit is very distinctive and can not be mistaken for any other mineral.
Marcasite has been known to pseudomorph other minerals. A pseudomorph is an atom by atom replacement of one mineral's chemistry for another. If done subtly, the replacement can leave the old mineral's shape intact. The effect is one mineral in the shape of another, hence the term pseudomorph (Latin for false shape). Marcasite has pseudomorphed pyrite, gypsum, fluorite and others. At other times marcasite is pseudomorphed itself into the iron oxide mineral goethite. Often the replacement is only peripheral and leaves a thin skin of iron oxides on the crystals. These iron oxides are seen as an iridescence sheen and can provide marcasite specimens with quite an attractive and colorful appearance. These oxides may also have a positive effect in slowing marcasite's unfortunate deterioration.
Over a period of years, marcasite will oxidize in collections, freeing sulfur which forms sulfuric acid. The acid will then attack the paper label and even the cardboard box holding the specimen. Over a period of decades, most marcasite specimens will have disintegrated into an undesirable dust along with deteriorated paper scraps. A sulfur smell released during this reaction is often the easiest characteristic distinguishing Marcasite from Pyrite. The reaction is triggered by exposure to air and is an exothermic reaction, meaning that the reaction releases heat. This does not mean that marcasite hand specimens will feel warm to the touch, but in some marcasite rich portions of certain mines the mine walls would get too hot to touch because of this reaction. Ironically, specimens with iridescent oxide coatings have shown a resistance to deterioration and seem to survive longer than "fresh" maracasites. Either way marcasite is an interesting and attractive mineral and even with the slow deterioration can be a pleasure to own for many many years.
Marcasite can be formed as both a primary or a secondary mineral. It typically forms under low-temperature highly acidic conditions. It occurs in sedimentary rocks (shales, limestones and low grade coals) as well as in low temperature hydrothermal veins. Commonly associated minerals include pyrite, pyrrhotite, galena, sphalerite, fluorite, dolomite and calcite.[1]
As a primary mineral it forms nodules, concretions and crystals in a variety of sedimentary rock, such as at Dover, Kent, England, where it forms as sharp individual crystals and crystal groups, and nodules (similar to those shown here) in chalk.
As a secondary mineral it forms by chemical alteration of a primary mineral such as pyrrhotite or chalcopyrite.
Marcasite reacts more readily than pyrite under conditions of high humidity. The product of this disintegration is iron(II) sulfate and sulfuric acid. The hydrous iron sulfate forms a white powder consisting of the mineral melanterite, FeSO4·7H2O.[5]
This disintegration of marcasite in mineral collections is known as "pyrite decay". When a specimen goes through pyrite decay, the marcasite reacts with moisture and oxygen in the air, the sulfur oxidizing and combining with water to produce sulfuric acid that attacks other sulfide minerals and mineral labels. Low humidity (less than 60%) storage conditions prevents or slows the reaction.[6]